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First page of “STPM Chemistry (Semester 2) -1 - STPM CHEMISTRY SEMESTER 2 PRE-EXAM PRACTICE”

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STPM Chemistry (Semester 2) -1 - STPM CHEMISTRY SEMESTER 2 PRE-EXAM PRACTICE

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Section A: Structured Questions Answer all questions. 1 (a) Chrome yellow has been used for a long time as a yellow pigment in oil paintings. SO4 2-(aq) + 4H + (aq) + 2e ⇌ 2H2O(l) + SO2(g) E o = +0.17 V CrO4 2-(aq) + 8H + (aq) + 3e ⇌ 4H2O(l) + Cr 3+ (aq) E o = +1.33 V

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chemistry stpm sem 2 experiment 10

TITRIMETRIC MTHODS Titrimetric methods are widely used in chemistry to determine oxidants, reductants, acids, bases, metal ions, etc. Titration is based on a reaction between the analyte (unknown sample) and the regent of known concentration and reaction stoichiometry. The volume or mass of the reagent needed to react completely with a fixed quantity of the analyte is obtained from which the amount of analyte is determined. Titrimetric methods include powerful group of quantitative procedures that are based on measuring the amount of reagent consumed by the analyte. These methods include, i. Volumetric titrimetry. This involves measuring volume of solution of known concentration that is needed to react completely with the sample. The reagent of exactly known concentration is refered to as standard reagent. Titration is the process in which the standard reagent is added to a solution of the sample until the reaction is judged to be complete. Back titration is the process by which the excess of the standard solution used to consume the sample is determined by titration with a second standard solution. Equivalence point and end-point are confused to mean the same but they are totally different. Equivalence point is a point in titration when the amount of standard solution added is exactly equal to the amount of the sample whereas end-point is the point in titration when a physical change occurs that is associated with a condition of chemical equivalence. The two values are usually different and the difference gives the titration error. Indicators are added to the solution mixtures to produce an observable physical change at the end-point or near equivalence point ii. Gravimetric titrimetry. This involves measuring mass of reagent that reacts completely with the sample. iii. Coulometric titrimetry. Here the reagent is a constant direct electrical current of known magnitude that consumes the sample. Here the time is required, and the total charge to complete the electrochemical reaction

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STPM Semester 1 Chemistry Experiment 2 Volumetric Analysis - Acid Base and redox

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    Experiment 2: Acid-Base Titration - Determination Of The Concentration Of Hydrochloric Acid Solution. ... STPM 2022 - 962/2/P. Section A [15 marks] Answer all questions in this section. The standard enthalpies of combustion for H 2 , C 6 H 10 and C 6 H 12 are - 286 kJ mol- 1 , - 3754 kJ mol- 1 and - 3920 kJ mol- 1 respectively ...

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